Which set of the following gases is most important for green

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Which set of the following gases is most important for greenhouse effect ?

[UKPSC 2016 GS P1]

Carbon dioxide, Methane, Chlorine, Nitric oxide.

Nitric oxide, Methane, Ethane, Chlorfluoro carbons.

Carbon dioxide, Methane, Nitrous oxide, Water vapour.

Carbon Monoxide, Sulphur dioxide, Methane, Water vapour